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You can link your cells to XML Map elements using Aspose.Cells. Please use the Cells.LinkToXmlMap() method for this purpose.
The following sample code loads the source Excel file, which contains an XML map, and then links cells A1, B2, C3, D4, E5, and F6 to XML Map elements FIELD1, FIELD2, FIELD4, FIELD5, FIELD7, and FIELD8, respectively, and then saves the workbook in the output Excel file.
If you open the output Excel file and click the Developer > Source button, you will see that the cells are linked to XML Map elements and they will also be highlighted by Microsoft Excel as shown in this image.

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