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You can set the values format code of chart series using the Series.ValuesFormatCode property. This property is not only useful for series that are based on a range inside the worksheet but also works well for series created from an array of values.
The following sample code adds a series to an empty chart that previously had no series. It adds the series using an array of values. After adding the series, it formats it with the code $#,##0 using the Series.ValuesFormatCode property, and the number 10000 becomes $10,000. The screenshot shows the effect of the code on the sample Excel file and the output Excel file after execution.

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